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Because honey is a natural sweetener, it contains trace minerals and vitamins that refined sugar does not have as well as antioxidant properties. Also, the body takes longer to absorb honey, making it a *slightly* healthier choice.
There is no hard fast rule for substituting honey for sugar in a recipe. It is a matter of trial and error. Honey is sweeter and wetter, so in general, you can use less of it and reduce the liquid content as well.
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